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101.
Gas/particle partitioning of atmospheric PCDD/Fs in a satellite town in Eastern China 总被引:3,自引:0,他引:3
Meng-xia Xu Jian-hua Yan Sheng-yong Lu Xiao-dong Li Tong Chen Ming-jiang Ni Hui-fen Dai Fei Wang Ke-fa Cen 《Chemosphere》2009,76(11):1540-1549
Gas/particle partitioning of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) in ambient air was investigated in a satellite town in Eastern China from April 2007 to January 2008 comprehending large temperature variations (from 3 to 34 °C, daily average). Molecular weight, molecular structure and ambient temperatures are the three major factors that govern the gas/particle partitioning of atmospheric PCDD/Fs throughout the year. Generally, good agreements were obtained (except for winter) between measured particulate fractions and theoretical estimates of both the Junge–Pankow adsorption model and Harner Bidleman absorption model using different sets of subcooled liquid vapor pressure and octanol–air partition coefficient (Koa), respectively. Models utilizing estimates, derived from gas chromatographic retention indices (GC-RIs), are more accurate than that of entropy-based. Moreover, during winter, the Koa-based model using the GC-RIs approach performs better on lower chlorinated PCDD/Fs than that of -based. Furthermore, possible sources of mismatch between measured and predicted values in winter (3–7 °C) were discussed. Gas adsorption artifact was demonstrated to be of minor importance for the phenomena observed. On the other hand, large deviations of slopes (mr) and intercepts (br) in logKp vs. plots from theoretical values are observed in the literature data and these are found to be linearly correlated with ambient temperatures (P<0.001) in this study. This indicates that the non-equilibrium partitioning of PCDD/Fs in winter may be significantly influenced by the colder temperatures that may have slowed down the exchange between gaseous and particulate fractions. 相似文献
102.
采用改性沸石分离富集-火焰原子吸收光谱法测定长江水中微量镉,优化了富集和洗脱条件,讨论了干扰离子的影响。方法在0μg~4.00μg范围内线性良好,检出限为0.214μg/L,长江水平行测定的RSD为1.8%,加标回收率为99.0%~104%。 相似文献
103.
Celia Arenas Carlos Leiva Luis F. Vilches Héctor Cifuentes 《Waste management (New York, N.Y.)》2013,33(11):2316-2321
The present study aims to determine and evaluate the applicability of a new product consisting of coal bottom ash mixed with Portland cement in the application of highway noise barriers. In order to effectively recycle the bottom ash, the influence of the grain particle size of bottom ash, the thickness of the panel and the combination of different layers with various particle sizes have been studied, as well as some environmental properties including leachability (EN-12457-4, NEN-7345) and radioactivity tests. Based on the obtained results, the acoustic properties of the final composite material were similar or even better than those found in porous concrete used for the same application. According to this study, the material produced presented no environmental risk. 相似文献
105.
本文研究了用乙二胺铜(Ⅱ)—氯仿作为络合—萃取体系,石墨炉原子吸收技术间接测定水中痕量阴离子洗涤剂的一种方法。其检出限为2.0ug/1,加标回收率为89.6%~104.5%。具有选择性好、灵敏度高、快速简便等特点。同时还研究了水样的酸度和共存离子对测定的影响。对于用原子吸收进行有机分析具有一定的实际意义。 相似文献
106.
剥壳机生产系统将胡豆打碎和去壳时发出严重的扰民噪声,对产生噪声的设备和管道采用隔声和吸声控制措施。结果表明,效果十分明显,达到了国家环境噪声排放标准。 相似文献
107.
估计近场地震动的统计—经验格林函数法 总被引:3,自引:0,他引:3
本文提出统计-经验格林函数法,用以估计缺乏小震记录场点在大震时的地震动时程。统计-经验格林函数的富里哀幅值谱从其它类似场地获得的小震记录的富里哀谱的衰减关系中得到,其相位谱则直接取自小震记录的相位谱。本文分别用经验格林函数法和统计-经验格林函数法,用迁安台记录到的1976年唐山地震的三次余震(M_L 5.8、M_L 5.7和M_L 5.4)的加速度记录,合成唐山地震的最大余震滦县地震(M_s 7.1)时迁安台的加速度时程曲线,合成结果说明了所提方法的可行性。 相似文献
108.
109.
Effects of Starch Moisture on Properties of Wheat Starch/Poly(Lactic Acid) Blend Containing Methylenediphenyl Diisocyanate 总被引:2,自引:0,他引:2
Methylenediphenyl diisocyanate was found to improve the interfacial interaction between poly(lactic acid)(PLA) and granular starch. The objective of this research was to study the effect of starch moisture content on the interfacial interaction of an equal-weight blend of wheat starch and PLA containing 0.5% methylenediphenyl diisocyanate by weight. Starch moisture (10% to 20%) had a negative effect on the interfacial binding between starch and PLA. The tensile strength and elongation of the blend both decreased as starch moisture content increased. At 20% moisture level, the starch granules embedded in the PLA matrix were observed to be swollen, resulting in poor strength properties and high water absorption by the blend. 相似文献
110.
利用正交试验设计,以光谱预处理、特征筛选及多元校正方法为考察因素,每个因素的4种不同方法为水平,确定了水中3种苯系物(苯酚、苯胺及苯甲酸)紫外光谱数据的最佳分析方法,从而建立了其定量校正模型。对于苯酚、苯胺及苯甲酸,其光谱预处理、特征筛选及多元校正分别采用一阶导数+无信息变量消除法(UVE)+偏最小二乘回归(PLSR),Savitzky-Golay平滑+变量结合种群分析法(VCPA)+PLSR,Savitzky-Golay平滑+移动窗口偏最小二乘法(MWPLS)+PLSR。在独立测试集上3组分的预测误差均方根(RMSEP)分别为0.809 4、0.796 3和0.945 4。水样加标回收实验的回收率为97.79%~103.84%,相对标准偏差(RSD)小于3%。该方法可作为一种同时测定水中苯系物的简便有效方法。 相似文献